李粟,苗海斌,康富华

• 1:石家庄市环境监测中心

摘要(Abstract)：

对2013年春季石家庄市PM10和PM2.5中水溶性离子进行分析,石家庄市春季PM10平均质量浓度为354.9μg/m3,总水溶性无机离子质量浓度为105.48μg/m3,其中SO2-4,NH+4,Ca2+,Cl-和NO-3是主要的水溶性无机离子,占总离子质量分数依次为40.89%,17.93%,13.49%,10.75%和9.09%,共计92.15%;PM2.5平均质量浓度为174.4μg/m3,总水溶性无机离子质量浓度为86.45μg/m3,与PM10中一样,SO2-4,NH+4,Cl-,NO-3和Ca2+是主要的水溶性无机离子,占总离子质量分数依次为41.06%,24.25%,12.11%,8.34%和5.32%,共计91.08%。石家庄市春季PM10及PM2.5中NO-3/SO2-4比值分别约为0.22和0.20,由此判断石家庄市春季主要污染以固定源为主,以燃煤及工业生产为主要来源。

关键词(KeyWords)： 固体污染防治工程;石家庄市;PM10;PM2.5;水溶性离子

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 李粟,苗海斌,康富华

参考文献(References)：

• [1]CHAN Y C,SIMPSON R W,MCTAINSH G H,et al.Source apportionment of visibility degradation problems in Brisbane(Australia)using the multiple linear regres-sion techniques[J].Atmospheric Environment,1999,33(19):3237-3250.
• [2]FULLER K,MALTA W,KREIDENWEIS S.Effects of mixing on extinction by carbonaceous particles[J].Journal of Geophysical Research,l999,104(15):94l-954.
• [3]翟红兵,魏鹏冉,张小林.石家庄市大气污染现状及污染特征分析[J].河北工业科技,2013,30(4):301-305.ZHAI Hongbing,WEI Pengran,ZHANG Xiaolin.Air pollution status and characteristics of Shijiazhuang City[J].Hebei Journal of Industrial Science and Technology,2013,30(4):301-305.
• [4]樊文雁.北京及周边地区大气污染初步研究[D].兰州:兰州大学,2008.FAN Wenyan.A Pimary Study on Air Pollution in Beijing and Its Surrounding Area[D].Lanzhou:Lanzhou University,2008.
• [5]李国翠,王建国,连志鸾.石家庄大气污染与沙尘天气的关系分析[J].气象与环境学报,2007,23(2):1-5.LI Guocui,WANG Jianguo,LIAN Zhiluan.Relationship between atmospheric pollution and sandy weather in Shijiazhuang[J].Journal of Meteorology and Environment,2007,23(2):1-5.
• [6]贺克斌,杨复沫,段凤魁,等.大气颗粒物与区域复合污染[M].北京:科学出版社,2011.HE Kebin,YANG Fumo,DUAN Fengkui,et al.Atmospheric Particulate Matter and Regional Compound Pollution[M].Beijing:Science Press,2011.
• [7]徐虹,张晓勇,毕晓辉,等.中国PM2.5中水溶性硫酸盐和硝酸盐时空变化特征[J].南开大学学报,2013,46(6):32-40.XU Hong,ZHANG Xiaoyong,BI Xiaohui,et al.Spatial and season distribution characteristics of sulfate and nitrate in PM2.5of China[J].Acta Scientiarum Naturalium Universitatis Nankaiensis,2013,46(6):32-40.
• [8]杨周,李晓东,于静,等.成都市冬季不同粒径大气颗粒物水溶性无机离子的变化特征[J].生态学杂志,2013,32(3):682-688.YANG Zhou,LI Xiaodong,YU Jing,et al.Variation characteristics of water-soluble inorganic ions in size-segregated atmospheric particles in Chengdu in winter[J].Chinese Journal of Ecology,2013,32(3):682-688.
• [9]WANG Y,ZHUANG G S,ZHANG X Y,et al.The ion chemistry,seasonal cycle,and sources of PM2.5and TSP aerosol in Shanghai[J].Atmos Environ,2006,40(16):2935-2952.
• [10]张建国,赵博,付志涛,等.石家庄市环保产业的现状与对策研究[J].河北工业科技,2013,30(4):276-279.ZHANG Jianguo,ZHAO Bo,FU Zhitao,et al.Analysis of the current situation and countermeasure of Shijiazhuang environmental protection industry[J].Hebei Journal of Industrial Science and Technology,2013,30(4):276-279.
• [11]李彩霞,李彩亭,曾光明,等.长沙市夏季PM10和PM2.5中水溶性离子的污染特征[J].中国环境科学,2007,27(5):599-603.LI Caixia,LI Caiting,ZENG Guangming,et al.Pollution characteristics of water-soluble ions in atmospheric PM10and PM2.5 in Changsha in summer[J].China Environmental Science,2007,27(5):599-603.
• [12]范瑜,邹塞.徐州市春季PM10及PM2.5污染来源分析[J].环境科技,2014,27(2):49-52.FAN Yu,ZOU Sai,Analysis of the PM10and PM2.5pollution sources of Xuzhou on spring[J].Environmental Science and Technology,2014,27(2):49-52.
• [13]邱天雪,陈进生,尹丽倩,等.闽南重点城市春季PM2.5中水溶性无机离子特征研究[J].生态环境学报,2013,22(3):512-516.QIU Tianxue,CHEN Jinsheng,YIN Liqian,et al.Study on the characteristics of water-soluble inorganic ions in PM2.5in spring in the key citis of southern Fujian[J].Ecology and Environmental Sciences,2013,22(3):512-516.
• [14]胡敏,赵云良,何凌燕,等.北京冬、夏季颗粒物及其离子成分质量浓度谱分布[J].环境科学,2005,26(4):1-6.HU Min,ZHAO Yunliang,HE Lingyan,et al.Mass size distribution of Beijing particulate matters and its inorganic water-soluble ions in winter and summer[J].Environmental Sciences,2005,26(4):1-6.
• [15]夏立江.环境化学[M].北京:中国环境科学出版社,2003.XIA Lijiang,Environmental Chemistry[M].Beijing:China Environmental Science Press,2003.