基于SPAMS的石家庄市2018年春节期间重污染过程研究Study on the process of heavy pollution during Spring Festival in Shijiazhuang City in 2018 based on a single particle aerosol mass spectrometer
程丽萍,李嘉欣,赵纲,李雪菲,王玮
摘要(Abstract):
2018年2月15日—2月21日春节假期,石家庄市出现了2月份以来污染最重、持续时间最长的一次空气污染过程。为探究重污染天气成因,采用位于石家庄市大气自动监测站的单颗粒气溶胶质谱仪(SPAMS),对春节期间的细颗粒物化学组成进行了分析,结合空气质量状况及气象条件等因素,对重污染天气的成因进行了推定。结果表明,在此次污染过程期间,地面持续处于低压幅合,边界层低,逆温现象严重,致使18日和19日的污染物浓度累积升高;同时根据SPAMS污染特征分析可知,春节期间发生的重污染过程中,燃煤和工业工艺源的累积,加剧了二次转化,且随着PM2.5浓度的攀升,细颗粒物中重金属和矿尘颗粒占比有一定的增加,二次无机源和烟花源的贡献变化较为突出。研究石家庄市春节期间大气污染物的组成及其成因,可为科学有效地制定大气环境调控策略提供技术参考。
关键词(KeyWords): 大气污染防治工程;SPAMS;组分分析;重污染天气;石家庄市;春节
基金项目(Foundation): 2017年石家庄市第二批指导计划项目(171242403)
作者(Author): 程丽萍,李嘉欣,赵纲,李雪菲,王玮
参考文献(References):
- [1]曹鹏,王路光,崔立昌,等.河北省大气污染状况分析及防治对策探讨[J].煤炭与化工,2014,37(8):144-152.CAO Peng,WANG Luguang,CUI Lichang,et al.Analysis of atmospheric pollution and countermeasures in Hebei province[J].Coal and Chemical Industry,2014,37(8):144-152.
- [2]石家庄市人民政府.我市印发《2017—2018年秋冬季大气污染综合治理攻坚行动方案》“40条”硬措施改善空气质量[EB/OL].http://new.sjz.gov.cn/col/1490690576707/2017/09/29/1506642236933.html,2017-09-29.
- [3]环境保护部.环境保护部通报2017年10—12月京津冀大气污染传输通道城市空气质量状况[EB/OL].http://www.zhb.gov.cn/gkml/hbb/qt/201801/t20180110_429445.htm,2018-01-10.
- [4]环境保护部.大气颗粒物来源解析技术指南(试行)[EB/OL].http://www.mee.gov.cn/hjzli/dqwrfz/dqklwyjx/201605/P020160525705471045605.pdf,2018-07-10.
- [5]王彤,华阳,许庆成,等.京津冀郊区站点秋冬季大气PM2.5来源解析[J].环境科学,2019(3):1-10.WANG Tong,HUA Yang,XU Qingcheng,et al.Source apportionment of PM2.5in suburban area of Beijing-TianjinHebei region in autumn and winter[J].Environmental Science,2019(3):1-10.
- [6]索娜卓嘎,谭丽,周芮平,等.采暖期北京大气PM2.5中碳组分的分布特征及来源解析[J].中国环境监测,2018,34(4):54-59.SUO Nazhuoga,TAN Li,ZHOU Ruiping,et al.Distribution characteristics and sources apportionment of carbonaceous components in PM2.5during the heating periods in Beijing[J].China Environmental Monitoring,2018,34(4):54-59.
- [7]郭志明,刘頔,林田,等.太原城区PM2.5中多环芳烃、硝基多环芳烃的污染特征、来源解析和健康风险评价[J].环境科学学报,2018,38(3):1102-1108.GUO Zhiming,LIU Di,LIN Tian,et al.Concentration,source identification,and exposure risk assessment of PM2.5-bound PAHs and nitro-PAHs in the atmosphere of Taiyuan[J].Journal of Environmental Science,2018,38(3):1102-1108.
- [8]陈璐,赵东风,薛建良,等.环境空气中PM2.5的分布特征及来源解析[J].现代化工,2013,33(9):5-8.CHEN Lu,ZHAO Dongfeng,XUE Jianliang,et al.Distribution characterization and source apportionment of PM2.5in China[J].Modern Chemical Industry,2013,33(9):5-8.
- [9]周静博,李治国,路娜,等.抗战胜利70周年大阅兵期间石家庄大气细颗粒物在线来源解析[J].环境科学,2016,37(8):2855-2862.ZHOU Jingbo,LI Zhiguo,LU Na,et al.Online sources about atmospheric fine particles during the 70th anniversary of victory parade in Shijiazhuang[J].Environmental Science,2016,37(8):2855-2862.
- [10]郑玫,张延君,闫才青,等.中国PM2.5来源解析方法综述[J].北京大学学报(自然科学版),2014,50(6):1141-1154.ZHENG Mei,ZHANG Yanjun,YAN Caiqing,et al.Review of PM2.5source apportionment methods in China[J].Journal of Peking University(Natural Science Edition),2014,50(6):1141-1154.
- [11]周静博,任毅斌,洪纲,等.利用SPAMS研究石家庄市冬季连续灰霾天气的污染特征及成因[J].环境科学,2015,36(11):3972-3980.ZHOU Jingbo,REN Yibin,HONG Gang,et al.Characteristics and formation mechanism of a multi-day haze in the winter of Shijiazhuang using a single particle aerosol mass spectrometer(SPAMS)[J].Environmental Science,2015,36(11):3972-3980.
- [12]李治国,周静博,路娜,等.利用单颗粒气溶胶质谱仪研究石家庄市采暖结束前后大气细颗粒物污染特征及成因[J].科学技术与工程,2017,17(14):110-119.LI Zhiguo,ZHOU Jingbo,LU Na,et al.Research on characteristics and formation mechanism of Shijiazhuang PM2.5pollution during and after heating period using SPAMS[J].Science Technology and Engineering,2017,17(14):110-119.
- [13]黄子龙,曾立民,董华斌,等.利用SPAMS研究华北乡村站点(曲周)夏季大气单颗粒物老化与混合状态[J].环境科学,2016,37(4):1188-1198.HUANG Zilong, ZENG Limin, DONG Huabin,et al.Analysis of single particle aging and mixing state at an agriculture site(Quzhou)in the North China plain in summer using a single particle aerosol mass spectrometer[J].Environmental Science,2016,37(4):1188-1198.
- [14]刘浪,张文杰,杜世勇,等.利用SPAMS分析北京市硫酸盐、硝酸盐和铵盐季节变化特征及潜在源区分布[J].环境科学,2016,37(5):1609-1618.LIU Lang,ZHANG Wenjie,DU Shiyong,et al.Seasonal variation characteristics and potential source contribution of sulfate,nitrate and ammonium in Beijing by using single particle aerosol mass spectrometry[J].Environmental Science,2016,37(5):1609-1618.
- [15]王苏蓉,喻义勇,王勤耕,等.基于PMF模式的南京市大气细颗粒物源解析[J].中国环境科学,2015,35(12):3535-3542.WANG Surong,YU Yiyong,WANG Qingeng,et al.Source apportionment in Nanjing by PMF[J].China Environmental Science,2015,35(12):3535-3542.
- [16]闫璐璐,刘焕武,黄学敏,等.利用SPAMS研究西安市重污染天气的污染特征及来源[J].环境科学研究,2018,31(11):1841-1848.YAN Lulu,LIU Huanwu,HUANG Xuemin,et al.The characteristics and source apportionment of fine particles in Xi'an using a single particle aerosol mass spectrometer(SPAMS)during heavy pollution[J].Research of Environmental Sciences,2018,31(11):1841-1848.
- [17]周静博,张涛,李治国,等.利用SPAMS构建石家庄市PM2.5固定排放源成分谱库[J].河北工业科技,2015,32(5):443-450.ZHOU Jingbo,ZHANG Tao,LI Zhiguo,et al.Establishment of stationary source spectral library of PM2.5 by SPAMS in Shijiazhuang City[J].Hebei Journal of Industrial Science and Technology,2015,32(5):443-450.
- [18]洪纲.基于单颗粒质谱技术的石家庄市2016年秋季空气重污染成因分析[J].科学技术与工程,2018,18(9):348-354.HONG Gang.Causes analysis of heavy pollution weather in autumn of Shijiazhuang in 2016based on the single particle mass spectrometry[J].Science Technology and Engineering,2018,18(9):348-354.
- [19]崔明明,王雪松,苏杭,等.广州地区大气可吸入颗粒物的化学特征及来源解析[J].北京大学学报(自然科学版),2008,44(3):459-466.CUI Mingming,WANG Xuesong,SU Hang,et al.Chemical characters and sources identification of PM10in Guangzhou area[J]. ActaScientiarumNaturaliumUniversitatis Pekinensis,2008,44(3):459-466.
- [20]GB3095—2012,环境空气质量标准[S].
- [21]何俊杰,张国华,王伯光,等.鹤山灰霾期间大气单颗粒气溶胶特征的初步研究[J].环境科学学报,2013,33(8):2098-2104.HE Junjie, ZHANG Guohua, WANG Boguang,et al.Analysis of single particle characteristics during haze events in Heshan[J].Acta Scientiae Circumstantiae,2013,33(8):2098-2104.
- [22]陈多宏,李梅,黄渤,等.区域大气细粒子污染特征及快速来源解析[J].中国环境科学,2016,36(3):651-659.CHEN Duohong,LI Mei,HUANG Bo,et al.The pollution characteristicsandsourceapportionmentofregional atmospheric fine particles[J].China Environmental Science,2016,36(3):651-659.
- [23]LI Lei,HUANG Zhengxu,DONG Junguo,et al.Real time bipolar time-of-flight mass spectrometer for analyzing single aerosol particles[J].International Journal of Mass Spectrometry,2011,303(2):118-124.
- [24]付怀于,闫才青,郑玫,等.在线单颗粒气溶胶质谱SPAMS对细颗粒物中主要组分提取方法的研究[J].环境科学,2014,35(11):4070-4077.FU Huaiyu,YAN Caiqing,ZHENG Mei,et al.Application of on-line single particle aerosol mass spectrometry(SPAMS)for studying major components in fine particulate matter[J].Environmental Science,2014,35(11):4070-4077.
- [25]王宇骏,李梅,吴清柱,等.广州秋季灰霾生消过程气溶胶单颗粒组成特征研究[J].生态环境学报,2016,25(4):614-620.WANG Yujun,LI Mei,WU Qingzhu,et al.Characterizing single particle aerosols during the formation and removal of a haze event in the autumn of Guangzhou[J].Ecology and Environmental Sciences,2016,25(4):614-620.
- [26]李梅,李磊,黄正旭,等.运用单颗粒气溶胶质谱技术初步研究广州大气矿尘污染[J].环境科学研究,2011,24(6):632-636.LI Mei,LI Lei,HUANG Zhengxu,et al.Preliminary study of mineral dust particle pollution using a single particle aerosol mass spectrometer(SPAMS)in Guangzhou[J].Environmental Scientific Research,2011,24(6):632-636.
- [27]黄正旭,李梅,李磊,等.单颗粒气溶胶质谱仪研究进展[J].上海大学学报(自然科学版),2011,17(4):562-566.HUANG Zhengxu,LI Mei,LI Lei,et al.Progress in research of single particle aerosol mass spectrometer[J].Journal of Shanghai University(Natural Science Edition),2011,17(4):562-566.
- [28]LI M,DONG J G,HUANG Z X,et al.Analysis of cigarette smoke aerosol by single particle aerosol mass spectrometer[J].Chinese Journal of Analytical Chemistry,2012(6):936-939.
- [29]李梅,毕燕茹,黄正旭,等.在线单颗粒气溶胶质谱在大气重金属铅污染事故中的应用研究[J].中国环境监测,2015,31(6):118-124.LI Mei,BI Yanru,HUANG Zhengxu,et al.Application of online single particle aerosol mass spectrometry on atmospheric lead pollution accidents[J].Environmental Monitoring in China,2015,31(6):118-124.
- [30]廖乾邑,陈建文,罗彬,等.颗粒物源解析研究进展与展望[J].资源节约与环保,2015(11):136.
- [31]李磊,谭国斌,张莉,等.运用单颗粒气溶胶质谱仪分析柴油车排放颗粒物[J].分析化学,2013,41(12):1831-1836.LI Lei,TAN Guobin,ZHANG Li,et al.Analysis of diesel exhaustparticlesusingsingleparticleaerosolmass spectrometry[J].Chinese Journal of Analytical Chemistry,2013,41(12):1831-1836.
- [32]喻义勇,王苏蓉,秦玮.大气细颗粒物在线源解析方法研究进展[J].环境监测管理与技术,2015,27(3):12-17.YU Yiyong, WANG Surong, QIN Wei.Progresses and perspectives of on-line source apportionments of PM2.5[J].The Administration and Technique of Environmental Monitoring,2015,27(3):12-17.
- [33]张尚鹏,廉丽姝,张文华.日照市空气质量变化特征及其与气象条件的关系[J].曲阜师范大学学报(自然科学版),2018,44(4):106-110.ZHANG Shangpeng,LIAN Lishu,ZHANG Wenhua.Characteristics of air quality in Rizhao and its relationships with meteorological conditions[J].Journal of Qufu Normal University(Natural Science Edition),2018,44(4):106-110.
- [34]尹晓梅,李梓铭,熊亚军,等.2014—2017北京市气象条件和人为排放变化对空气质量改善的贡献评估[J/OL].环境科学,2019(3):1-3[2018-12-13].YIN Xiaomei,LI Ziming,XIONG Yajun,et al.Contribution assessment of meteorology conditions and emission charge for air quality improvement in Beijing during 2014—2017[J/OL].Environmental Science,2019(3):1-23[2018-12-13].
- [35]娄拴柱,刘乙淼,任春雷,等.基于卫星遥感及SPAMS的石家庄市2017年秋冬季首次污染过程研究[J].河北工业科技,2018,35(5):354-362.LOU Shuanzhu,LIU Yimiao,REN Chunlei,et al.Study on the firs pollution process in autumn-winter of 2017 in Shijiazhuang City based on satellite remote sensing and SPAMS[J].Hebei Journal of Industrial Science and Technology,2018,35(5):354-362.